Analitical determination of substances subject to authorization or restriction in detergents and cleaning products
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Keywords

detergent
cleaning product
authorization REACH
restriction REACH
phthalates
nonionic surfactants

How to Cite

Úbeda Ruiz, P. J., Sevilla Bernabeu, M. L., Saquero Martínez, M., Martínez Cánovas, M. J., Martínez López, C., & López Casares, R. (2015). Analitical determination of substances subject to authorization or restriction in detergents and cleaning products. Spanish Journal of Environmental Health, 15(2), 96–102. Retrieved from https://ojs.diffundit.com/index.php/rsa/article/view/762

Abstract

The presence of the phthalates di-n-dibutyl phthalate, bis(2-ethylhexyl) phthalate and benzyl butyl phthalate, the alkylphenols nonylphenol and nonylphenol ethoxylates, and 2-(2-Methoxyethoxy)ethanol (DEGME) was determined and quanti ed in 26 detergents and cleaning products for domestic use. These chemicals are subject to authorization and restriction (REACH Regulation). Chromatography was used for separation (reverse-phase liquid chromatography for phthalates and alkylphenols, and gas chromatography for glycol ethers), and mass spectrometry for detection. Phthalates were detected in all samples. Phthalate concentrations were below the authorization limit for mixtures. Nonylphenol was present in a concentration that was relatively lower than those of nonylphenol ethoxylates. Alkylphenol concentrations were below the restriction level on the sale and use of domestic cleaning products. DEGME concentrations were below the restriction level on the sale of cleaning products to the general public. In sum, the concentrations of the di erent analyzed substances were below the concentration levels requiring authorization or restriction under the REACH Regulation.
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